Crystal structure of bis(diisopropylammonium) cis -diiodidobis(oxolato-κ 2 O 1 , O 2 )stannate(IV) - Université de Bourgogne Accéder directement au contenu
Article Dans Une Revue Acta crystallographica Section E : Crystallographic communications [2015-...] Année : 2018

Crystal structure of bis(diisopropylammonium) cis -diiodidobis(oxolato-κ 2 O 1 , O 2 )stannate(IV)

Résumé

In the title compound, ((Pr2NH2)-Pr-i)(2)[SnI2(C2O4)(2)], which was prepared by reacting ((Pr2NH2+)-Pr-i)(2)center dot C2O42- with SnI4 in a 2:1 molar ratio in a mixed ethanol-acetonitrile solvent, the Sn atom is coordinated by two chelating oxalate ions and two iodide ions, with the latter in a cis configuration. In the crystal, the cations are linked to the anions by N-H center dot center dot center dot O and bifurcated N-H center dot center dot center dot(O, O) hydrogen bonds, generating [10 (1) over bar] chains.
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hal-01856673 , version 1 (12-04-2024)

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Bougar Sarr, Cheikh Abdoul Khadir Diop, Mamadou Sidibé, Yoann Rousselin. Crystal structure of bis(diisopropylammonium) cis -diiodidobis(oxolato-κ 2 O 1 , O 2 )stannate(IV). Acta crystallographica Section E : Crystallographic communications [2015-..], 2018, 74 (4), pp.502 - 504. ⟨10.1107/S2056989018003602⟩. ⟨hal-01856673⟩
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