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Article Dans Une Revue Chemical Communications Année : 2016

BODIPY atropisomer interconversion, face discrimination, and superstructure appending

Résumé

A strategy was developed to append sterically hindered apical pickets on both faces of the BODIPY platform to prevent stacking and aggregation. Ortho-substitution of both the meso-phenyl ring and the boron-bound catechol affords the right directionality to append pickets, achieve face discrimination, featuring two inter-convertible atropisomers, and is reminiscent of the picket-fence strategy in porphyrins.
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Dates et versions

hal-01399094 , version 1 (18-11-2016)

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Pierre-Emmanuel Doulain, Christine Goze, Ewen Bodio, Philippe Richard, Richard A. Decréau. BODIPY atropisomer interconversion, face discrimination, and superstructure appending. Chemical Communications, 2016, 52 (24), pp.4474 - 4477. ⟨10.1039/c5cc10526a⟩. ⟨hal-01399094⟩
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