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Article Dans Une Revue ChemistrySelect Année : 2021

Synthesis of P-Chirogenic Diphosphinotriazoles and Their Use in Asymmetric Catalysis

Résumé

The stereoselective synthesis of P-chirogenic diphosphinotriazoles using ephedrine methodology was described. The coordination behavior of these compounds as P,P-ligands has been demonstrated by the preparation as well as the spectroscopic and X-ray crystallographic analyses of a palladium complex. The efficiency of these new P-chirogenic diphosphines in the palladiumcatalyzed asymmetric allylic substitution reaction was also evaluated.

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hal-03292655 , version 1 (20-07-2021)

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Jérôme Bayardon, Yoann Rousselin, Raluca Malacea-Kabbara. Synthesis of P-Chirogenic Diphosphinotriazoles and Their Use in Asymmetric Catalysis. ChemistrySelect, 2021, ⟨10.1002/slct.202100617⟩. ⟨hal-03292655⟩
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